Cementation of Ni2+ ions from acidic sulfate solutions onto a rotating zinc disc
Identifieur interne : 000E44 ( Main/Exploration ); précédent : 000E43; suivant : 000E45Cementation of Ni2+ ions from acidic sulfate solutions onto a rotating zinc disc
Auteurs : L. Makhloufi [Algérie] ; B. Saidani [Algérie] ; C. Cachet [France] ; R. Wiart [France]Source :
- Electrochimica Acta [ 0013-4686 ] ; 1998.
Abstract
During cementation of Ni2+ ions onto a zinc electrode, the time-dependence of the concentration of Ni2+ ions was studied by atomic absorption spectroscopy. The electrode surface was analyzed by S.E.M. and the surface area was measured by electrochemical impedance spectroscopy. The cementation is shown to be a first-order reaction which is diffusion-controlled. The reaction rate is strongly affected by the increase in the electrode surface area with increasing cementation time.
Url:
DOI: 10.1016/S0013-4686(98)00006-1
Affiliations:
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Le document en format XML
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<front><div type="abstract" xml:lang="en">During cementation of Ni2+ ions onto a zinc electrode, the time-dependence of the concentration of Ni2+ ions was studied by atomic absorption spectroscopy. The electrode surface was analyzed by S.E.M. and the surface area was measured by electrochemical impedance spectroscopy. The cementation is shown to be a first-order reaction which is diffusion-controlled. The reaction rate is strongly affected by the increase in the electrode surface area with increasing cementation time.</div>
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